Oxidative Dehydrogenation of Propane in the Realm of Metal–Organic Frameworks

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چکیده

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Oxidative Dehydrogenation of Propane in the Realm of Metal–Organic Frameworks

Propylene (propene) is one of the most important feedstocks in the chemical industry. It is a starting material for the synthesis of a wide variety of commodity chemicals ranging from small molecules (cumene, isopropanol, acrylonitrile, acrylic acid, propylene oxide, and butyraldehyde) to polymers (most notably, polypropylene). In 2013, approximately 85 million tons of propylene were processed ...

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Fifteen distinct MgO–V2O5, MgO–MoO3, MgO–V2O5–MoO3, and V2O5–MoO3 compositions were prepared using sol–gel chemistry and their selectivities and conversions for propane oxidative dehydrogenation (ODH) to propylene were measured. The vanadates were more active than the molybdates at lower temperatures; however, the molybdates exhibited higher selectivities at similar conversions. An increase in ...

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ژورنال

عنوان ژورنال: ACS Central Science

سال: 2017

ISSN: 2374-7943,2374-7951

DOI: 10.1021/acscentsci.7b00013